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How to Find Valence Electrons (Step-by-Step, with Practice)

Valence electrons are the electrons in an atom’s outer shell. For main-group elements, read them from the group number.

3 steps, 1 worked example, 4 practice problems. About 10 minutes. Free.

The route · 3 steps

  1. Find the element on the periodic table.
  2. Read its group number (top of the column).
  3. Groups 1–2: valence = group. Groups 13–18: valence = group − 10. Helium: 2.
Start here

Periodic table

Valence electrons come from the group number. Tap any element.

Tap an element.

123456789101112131415161718Row11 shell22 shells33 shells44 shells55 shells66 shells77 shells57–7189–103

Swipe sideways for the full table.

Spot it

How to recognize a valence electron question

Asked for “valence electrons” or “outer-shell electrons” of a main-group element.

Clue words marked:

How many valence electrons does an oxygen atom have?

Not this type?

Step-by-step

Worked example: valence electrons in oxygen

The idea

Group number → valence electrons
GroupValence e⁻Example
11Na
22Mg
133Al
144C
155N
166O
177Cl
188 (He: 2)Ne
Skip groups 3–12 (transition metals): the simple rule doesn’t apply. Some books label the main groups 1A–8A; then the A number is the valence count (helium aside).
Oxygen atom: 2 inner electrons and 6 outer-shell valence electrons, highlighted in gold.
Oxygen is in row 2: 2 shells. 2 inner, 6 outer. Only the outer shell counts.
Same answer from the configuration
O: 1s² 2s² 2p⁴
highest shell (n = 2): 2 + 4 = 6
Valence = electrons in the highest-numbered shell.

Valence electrons

Outer shell only.

Oxygen: 6

Total electrons

Every electron.

Oxygen: 8

On the periodic table: groups: Na 1, Mg 2, Al 13, C 14, N 15, O 16, Cl 17, Ne 18.

Worked example · 3 steps

How many valence electrons does an oxygen atom have?

  1. 1
    Find it

    8O16.00On the periodic table: oxygen (O) is in group 16.

  2. 2
    Check the group range

    16 is in groups 13–18, so subtract 10.

  3. 3
    Subtract 10
    valence = 16 − 10 = 6
  4. ✓
    Answer

    Oxygen has 6 valence electrons.

    Oxygen atom with its 6 valence electrons highlighted in gold.
    The 6 gold electrons are the valence electrons.
Your turn

Valence electron practice problems

Try first, then check. Hints if you need them.

Problem 1 of 4 · warm-up

How many valence electrons does a sodium atom have?

Hint 1 · the clue

Find sodium’s group on the periodic table.

Hint 2 · the next move

Group 1: valence = group number.

Your path:

  1. Find Na
  2. Group 1
  3. Valence = 1
Answer

Answer: 1

Full worked solution

What you know: sodium.

  1. Sodium is in group 1.
  2. Groups 1–2: valence = group, so 1.
Sodium atom with its 1 valence electron highlighted in gold.
Sodium: 2, 8, 1.

11Na22.99On the periodic table: sodium (Na) is in group 1.

Answer: 1

Problem 2 of 4

How many valence electrons does a phosphorus atom have?

Hint 1 · the clue

Phosphorus is in groups 13–18 on the periodic table.

Hint 2 · the next move

Group 15: subtract 10.

Your path:

  1. Find P
  2. Group 15
  3. 15 − 10
Answer

Answer: 5

Full worked solution

What you know: phosphorus.

  1. Phosphorus is in group 15.
  2. 15 − 10 = 5.
Phosphorus atom with its 5 valence electrons highlighted in gold.
Phosphorus: 2, 8, 5.

15P30.97On the periodic table: phosphorus (P) is in group 15.

Answer: 5

Problem 3 of 4 · watch for the trap

How many valence electrons does a bromine atom have?

Hint 1 · the clue

Not 35. That’s every electron. Only the outer shell counts.

Hint 2 · the next move

Bromine’s group on the periodic table, minus 10.

Your path:

  1. Find Br
  2. Group 17
  3. 17 − 10
Answer

Answer: 7

Full worked solution

What you know: bromine.

  1. Bromine is in group 17.
  2. 17 − 10 = 7.

Watch out: the 3d¹⁰ electrons are inner electrons, not valence: [Ar] 3d¹⁰ 4s² 4p⁵ → 2 + 5 = 7.

Bromine atom with its 7 valence electrons highlighted in gold.
Bromine: 2, 8, 18, 7.

35Br79.90On the periodic table: bromine (Br) is in group 17.

Answer: 7

Problem 4 of 4 · exam-style wording

An element in period 3 has 3 valence electrons. What is its atomic number?

Hint 1 · the clue

Period = row (3 shells). 3 valence electrons = group 13.

Hint 2 · the next move

Find row 3, group 13 on the periodic table.

Your path:

  1. 3 valence → group 13
  2. Row 3
  3. Read its atomic number
Answer

Answer: 13 (aluminum)

Full worked solution

What you know: period 3, 3 valence electrons.

  1. 3 valence electrons means group 13 (13 − 10 = 3).
  2. Period 3, group 13 is aluminum: atomic number 13.
Aluminum atom: three shells, 2, 8, 3, with the 3 valence electrons highlighted in gold.
Aluminum: row 3 = 3 shells, 3 valence.

13Al26.98On the periodic table: aluminum (Al) sits in period 3, group 13, atomic number 13.

Answer: 13 (aluminum)

Watch out

Common valence electron mistakes